• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:

    公开号:SU1468404A3
    申请号:SU864027234
    申请日:1986-04-04
    公开日:1989-03-23
    发明作者:Энгельс Ганс-Вернер；Нойшеффер Карлгейнц；Шпильау Пауль
    申请人:Динамит Нобель Аг (Фирма)；
    IPC主号:
    专利说明:

    isopropionic powdered nitric acid with 50 wt.% silicon dioxide, loss of dissolution in 50% w / w potassium hydroxide and 200 g by reaction — the specific component consisting of 100 wt.% of a mixture of oxides, in wt.%: amorphous silicon dioxide, 75, alumina 24.7 and titanium dioxide O, 3, obtained as Q dust on a filter used in melt processing of bauxite, and 100 g of calcined, crushed bauxite with grain size less than 0.2 mm, containing wt.%; alu-J5 mini 87 oxide, silicon dioxide 1 and iron oxide 12 are fed to a vessel equipped with perforated d-com, containing parallel aluminum wires with a diameter of 0.2 mm, which are positioned tically at a distance of 0.6 cm from each other . Thus, the mass ratio of the alkali metal silicate solution and the reactive component is 1: 2. The solidification of the current feedstock is carried out at 85 ° C for 60 minutes. During the curing process, the surface of the wire is decomposed by alkali to form gaseous H0 hydrogen and locally dissipate heat. Removing the wires from the mold is removed. In this way, a molded article with a plurality of channels is manufactured. As a result of gas formation, the channels are significantly enlarged and covered with a layer of alumina hydrate. Several molded products are fed into the furnace heated to 700 ° C and then the temperature in the furnace 40 is adjusted to 750 ° C, as a result of which the alumina hydrate is converted to j-alumina. The molded product manufactured in this way supposedly (but supplied with known methods 5 compounds of noble metals, which are fixed on J-alumina.
    EXAMPLE 2 Example 1 is repeated, with the difference that a perforated 50 disk that holds aluminum wires in shape, fits a fitting that has an electrical contact at the passage points of the aluminum wires, which has a 55 current effect.
    When removing from the mold, it is not necessary to remove residual aluminum wires. The hollow channels are enlarged more than the molded product manufactured according to example 1,
    EXAMPLE 3 Example 1 is repeated, with the difference that 120 g of metakaoline containing 53% by weight of silica and 47% by weight of alumina are used as the reactive component, and curing is carried out at 60 ° C. Thus, the mass ratio of the alkali metal silicate solution to the reactive component is 1: 1.2. A molded product is obtained, which can be supplied with known techniques by compounds of noble metals, which are fixed on J-alumina.
    EXAMPLE 4 An example is repeated with the difference that 150 g of the electrostatic precipitator of a coal-fired power plant containing, in wt%, silicon dioxide 48, alumina .43, iron oxide B and oxide are used as the reactive component. calcium I. Thus, the mass ratio of the solution of alkali metal silicates and ash is l: i, 5. In addition, another 100 g of quartz flour is used as a filler. Heating of the molded article is carried out at 880 ° C. In this case, a molded article is obtained, which can be supplied with known methods and compounds of noble metals, which are fixed on Y-oxide aluminum.
    Froze An example is repeated with the difference that 80 g of the residue on the filter of the manufacturing process of melting mulite containing, in wt.%: SiOj 70, oxide al} omini 22, and iron oxide 8, is used as the reactive component, while curing is carried out at 120 C, and the yagrev of the molded article - at 600 C. Thus, the mass ratio of the alkali metal silicate solution and the reactive component is 1: 0.8. A molded article is obtained, which can be supplied with known techniques by compounds of noble metals, which are fixed on aluminum oxide,.
    EXAMPLE 6 An example is repeated with the difference that in addition, another 100 g of talcum is used as
    5l
    filler. At the same time (Yu.puchat molded product of the same quality as the product of example 1.
    Example. Example 1 is repeated with the difference that it is used as the reactive component. Only 100 g of calcined crushed bauxite containing .maye is used. %: alumina 87,


    SiOj 1 and iron oxide 12, which corresponds to a mass ratio to a solution of alkali metal silicates equal to 1: 1 o This produces a molded product of the same quality as the product of the example.
    Example Example 1 is repeated, with the difference that 160 g of a mixture of oxides of the indicated composition and 180 g of calcined bauxite of the specified composition are used as the reactive component, which corresponds to the mass ratio to the alkali metal silicate solution equal to 1: 3, A.
    A molded article is obtained, which can be supplied with known techniques by compounds of noble metals, which are fixed on y-alumina.
    Example 9. Example 1 is repeated, with the difference that 80 g of the residue on the filter of the process for producing the melting of mullite containing, wt.%, SiOj 70, alumina 12, iron oxide 5 and calcium oxide 13, is used as the reactive component; moreover, the curing is carried out at 00 ° C, and the heat of the molded product is at 700 ° C. Thus, the mass ratio of the alkali metal silicate solution and the reactive component is 1: 0.8. The molded resin is obtained.
    five
    five
    0
    0
    50
    cross section; in fig. 2 - the same, perspective view.
    The molded article is made with round-shaped sections of generally parallel hollow channels 1 in the hardened molding mass 2. The molded product can also be hollow channels extending from the cylindrical walls outgoing from the central inlet 3 and installed in the hardened molding mass 2 .
    The proposed method for the preparation of a carrier for a gas purification catalyst is simpler than the known process, since it eliminates the steps of drying, calcining and impregnating.
    权利要求:
    Claims (2)
    [1]
    Invention Formula
    one . The method of obtaining a carrier for the catalyst for the purification of gases based on alumina, which is a molded product with hollow channels, comprising the steps of feeding the raw material into a fluid form, heat treatment at elevated temperature, removing the molded product from the mold and heating the molded product to 600-880 A C, characterized in that, in order to simplify the process, the feedstock is supplied to the mold in the presence of aluminum rods or wires, and the feedstock is heat treated in the mold at 60-120 ° C, moreover, a mixture of a solution of alkali metal silicates and a reactive component containing 53% by weight of silica and 47% by weight of alumina or 1-75% by weight of dioxide is used as the starting material.
    A product that can be supplied with lime silicon, 12-87 wt.% oxide by aluminum methods of compounds of noble metals, which are fixed on J-alumina.
    The molded articles offered can be used for cleaning automobile exhaust gases.
    Fig, 1 shows a molded product of flat-cylindrical shape.
    mini and the rest of the impurities selected from the group comprising iron oxide, calcium oxide, titanium dioxide in a mass ratio of 1: 0.8-3.4.
    [2]
    2. The method according to 1, 1 and 2, so that the heat treatment is carried out with the application of electric current.
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    同族专利:
    公开号 | 公开日
    EP0203284A3|1988-11-02|
    DE3512586C2|1988-09-29|
    US4668659A|1987-05-26|
    JPH0559788B2|1993-08-31|
    EP0203284A2|1986-12-03|
    JPS61230735A|1986-10-15|
    DE3512586A1|1986-10-09|
    DE8510301U1|1985-10-24|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    GB343441A|1929-05-03|1931-02-16|Lloyd Francis Nickell|Improvements relating to catalyst carriers|
    US3755534A|1971-08-12|1973-08-28|Grace W R & Co|Catalytic control of auto exhaust emissions|
    JPS5322557B2|1973-04-13|1978-07-10|
    JPS5345687A|1976-10-06|1978-04-24|Toyota Motor Corp|Catalyst carrier and catalyst|
    US4189404A|1977-01-06|1980-02-19|Engelhard Minerals & Chemicals Corporation|Catalyst and process of its preparation|
    DE2935914A1|1979-09-06|1981-04-02|Kali-Chemie Ag, 3000 Hannover|METHOD FOR PRODUCING SPHERICAL SHAPED BODIES BASED ON AL 2 O 3 AND / OR SIO 2 |
    FR2517365B1|1981-11-27|1984-02-24|Pro Catalyse|DE3624934A1|1986-07-23|1988-01-28|Dynamit Nobel Ag|AT HIGH TEMPERATURES, CONSTANT CATALYST MOLDED BODIES AND METHOD FOR THE PRODUCTION THEREOF|
    US5210062A|1991-08-26|1993-05-11|Ford Motor Company|Aluminum oxide catalyst supports from alumina sols|
    DE4206310A1|1992-02-28|1993-09-02|Sperling Friedrich Dr Ing|Engine exhaust catalyst - made by moulding and cold hardening mixt. of catalyst and support materials|
    DE4322037A1|1993-07-02|1995-01-26|Bischoff Erhardt Gmbh Co Kg|Catalytic converter for internal combustion engines|
    DE4329558A1|1993-09-02|1995-03-09|Friedrich Dr Ing Sperling|Soot filter for diesel engines|
    JP4355469B2|2002-03-08|2009-11-04|日本碍子株式会社|Alumina-supported support, catalyst body, and method for producing alumina-supported support|
    DE112017005323T5|2016-10-21|2019-08-01|Cummins Emission Solutions Inc.|Substrate shape, geometry, positioning and / or cell density to improve post-treatment performance|
    法律状态:
    优先权:
    申请号 | 申请日 | 专利标题
    DE19858510301|DE8510301U1|1985-04-06|1985-04-06|Catalytic converter support made from inorganic molding compounds|
    DE19853512586|DE3512586C2|1985-04-06|1985-04-06|
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